تم الحل ✓
categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-14
السؤال
Transcribed Image Text:
Rates of Non-elementary reactions
Consider the following mechanism:
a. What is the net reaction?
Class Activity
k₁
2NO N₂02
K-1
k2
N2O2 + Cl2 2 NOCI
b. Which of the above species is an intermediate? Why?
c. Find the rate of the overall reaction using the steady-state approximation.
d. Repeat part (c) using the rate-determining step method, assuming the first-step is fast and
at equilibrium and the second step is slow.
2NO N2O2 (fast, at equilibrium)
k-1
k2
N20₂+ Cl22 NOCI (slow)
e. At what conditions the rate laws predicted by the steady-state approximation and by the
rate-determining step become identical.
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