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categoryالكيمياء
schoolبكالوريوس
event_available2026-07-14
السؤال
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A pressure cooker (a kitchen appliance) is a pot on which the top seals tightly, allowing pressure to build up inside. You put water in the pot and heat it to
boiling. At the higher pressure, water boils at a higher temperature and this allows food to cook at a faster rate. Most pressure cookers have a setting of 15
psi, which means that the pressure in the pot is 15 psi above atmospheric pressure (1 atm = 14.70 psi). Use the Clausius-Clapeyron equation to calculate
the temperature at which water boils in the pressure cooker. Enthalpy of water vaporization is 40.7 kJ/mol.
Temperature=
°C
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Compare the boiling points of the various isomeric hydrocarbons shown in the table below. Notice the relationship between boiling point and structure;
branched-chain hydrocarbons have lower boiling points than the unbranched isomer. Speculate on possible reasons for this trend. Why might the
intermolecular forces be slightly different in these compounds?
Compound
Boiling Point (°C)
Heptane
98.4
3-Ethylpentane
93.5
3-Methylhexane
92.0
2-Methylhexane
90.0
2,2,3-
81.7
Trimethylbutane
The more branched structure has smaller exposed surface and hence stronger dispersion intermolecular forces.
The more branched structure has smaller exposed surface and hence weaker dispersion intermolecular forces.
The more branched structure has larger exposed surface and hence stronger dispersion intermolecular forces.
The more branched structure has larger exposed surface and hence weaker dispersion intermolecular forces.
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