تم الحل ✓
categoryكيمياء
schoolبكالوريوس
event_available2026-07-14
السؤال
Transcribed Image Text:
The concentration of Cu2+ in seawater is determined by anodic stripping voltammetry at
a hanging mercury drop electrode after first releasing any copper bound to organic
matter. To a 25.00-mL sample of seawater 1 mL of 0.5 M HNO3 and 1 mL of 0.1%
H2O2 are added. The sample is irradiated with UV light for 6 hr and then diluted to
volume in a 50-mL volumetric flask. Deposition of Cu2+ takes place at -0.45 V versus
an SCE for 10 min, producing a peak current of 22.5 (arbitrary units). A second
25.00-mL sample of the seawater is treated identically, except that 0.5 mL of a 10.00
μM solution of Cu2+ is added, producing a peak current of 32.1 (arbitrary units). What is
the concentration of Cu2+ in seawater?
1.652 μM
0.365 μM
0.468 μM
1.352 μM
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