تم الحل ✓
categoryكيمياء
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
17-38. Peak current (Ip) and scan rate (v) are listed for cyclic
voltammetry of the reversible reaction Fe(II) → Fe(III) of a water-
soluble ferrocene derivative in 0.1 M NaCl. 59
N(CH3)
Scan rate (V/s)
0.019 2
Fe PF
0.048 9
0.075 1
0.125
0.175
0.251
Peak anodic current (A)
2.18
3.46
4.17
5.66
6.54
7.55
If a graph of I, versus Vv gives a straight line, then the reaction is
diffusion controlled. Prepare such a graph and use it to find the dif-
fusion coefficient of the reactant from Equation 17-21 for this one-
electron oxidation. The area of the working electrode is 0.020 1 cm²,
and the concentration of reactant is 1.00 mM.
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