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categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
The following reactions are carried out isothermally in a 50 dm3 PFR:
A+2B
C+D
FDI=DICAC
2D+3A
C+E
=K2CACD
B+2C >>D+F
=k₁CC
Additional information: Liquid phase
kp
0.25 dm/mol2 min
Uo 10 dm³/min
= 0.1 dm³/mol min
CAD
= 1.5 mol/dm³
K3 5.0 dm/mol²-min
Сво - 2.0 mol/dm³
(a) Plot the species concentrations and the conversion of A as a function of the distance (i. e.,
volume) clown a 50-dm3 PFR. Note any maxima.
(b) Determine the effluent concentrations and conversion from a 50-dm3 CSTR. (Ans: CA = 0.61
, CB = 0.79, CF = 0.25, and CD = 0.45 mol/dm3.)
(c) Plot the species concentrations and the conversion of A as a function of time when the
reaction is carried out in a semibatch reactor initially containing 40 dm3 of liquid. Consider two
cases: (I) A is fed to B, and (2) B is fed to A. What differences do you observe for these two
cases?
(d) Vary the ratio of B to A (I<OB<10) in the feed to the PFR and describe what you find. What
generalizations can you make from this problem?
(e) Rework this problem for the case when the reaction is a gas-phase reaction. We will keep
the constants the same so you won't have to make too many changes in your Polymath
program, but we will make u0 = 100 dm3/min, CTO = 0.4 mol/dm3, V = 500 dm3 and an
equimolar feed of A and B. Plot the molar flow rates and SC/D and SE/F clown a PFR.
(f) Repeat (e) when D diffuses out through the sides of a membrane reactor where the mass
transfer coefficient, KCD, can be varied between 0.1 min-1 and 10 min-1. What trends do you
find?
(g) Repeat (e) when B is feel through the sides of a membrane reactor.
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