تم الحل ✓
categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
A partial molar property of a component in a mixture may be either greater than or less
than the corresponding pure component molar property. Furthermore, the partial molar
property may vary with composition in a complicated way. Let's study in more detail a very
popular mixture: ethanol and water. Compute the (a) the partial molar volumes, and (b) the
partial molar enthalpies of ethanol and water in an ethanol-water mixture. Below are some
experimental data on this mixture provided by the International Critical Tables.
Heat Evolved on Mixing at
17.33°C (kJ/mol
Alcohol
wt%
Density at
20°C (kg m-³)
Mole%
x 10-³
Water
of Ethanol)
0
0.9982
5
0.9894
22222222222222
10
0.9819
15
0.9751
20
0.9686
25
0.9617
30
0.9538
35
0.9494
40
0.9352
45
0.9247
50
0.9138
0.9026
0.8911
0.8795
65
0.8677
0.8556
75
0.8434
85
0.8310
90
0.8180
90
95
0.8042
95
5052223242583R22222
0.042
10
0.092
15
0.167
0.251
0.335
0.423
0.519
0.636
0.757
0.946
1.201
1.507
1.925
70
2.478
3.218
4.269
5.821
7.801
9.818
100
0.7893
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