تم الحل ✓
categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
The elementary reversible liquid-phase reaction
A B
takes place in a CSTR with a heat exchanger. Pure A enters the reactor.
(a) Derive an expression (or set of expressions) to calculate G(T) as a function of heat of
reaction, equilibrium constant, temperature, and so on. Show a sample calculation for G(T) at T =
400 K.
(b) What are the steady-state temperatures? [Ans.: 310, 377, 418 K.]
(c) Which steady states are locally stable?
(d) What is the conversion corresponding to the upper steady state?
(e) Vary the ambient temperature Ta and make a plot of the reactor temperature as a function of
Ta, identifying the ignition and extinction temperatures.
(f) If the heat exchanger in the reactor suddenly fails (i.e., UA = 0), what would be the conversion
and the reactor temperature when the new upper steady state is reached? [Ans.: 431 K.]
(g) What heat exchanger product, UA, will give the maximum conversion?
(h) Write a question that requires critical thinking and then explain why your question requires
critical thinking. [Hint: See Preface Section B.2.]
(i) What is the adiabatic blowout flow rate, u0 ?
(j) Suppose that you want to operate at the lower steady state. What parameter values would you
suggest to prevent runaway, e.g., the upper SS?
Additional information
UA 3600 cal/min K
E/R
20,000 K
CP = CPB
=40 cal/mol K
V = 10 dm³
vo
1 dm³/min
FAO
10 mol/min
AH-80,000 cal/mol A
Ke 100 at 400 K
k 1 min at 400 K
Ambient temperature, T, = 37°C
Feed temperature. T₁ = 37°C
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