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categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
3. Use the Peng-Robinson (PR) equation of state to generate a pressure-volume diagram for carbon
dioxide at reduced temperature isotherms T, = T/T =0.8, 1.0, and 1.1. For CO₂, critical
-
temperature is 304.2 K, critical pressure is 73.76 bar, and acentric factor is 0.225. Make sure your
plot captures the critical point and vapor-liquid coexistence region of the P-v diagram.
Experimental values of the molar volume of carbon dioxide as a function of temperature and pressure
are available from NIST's Chemistry Webbook - Thermophysical Properties of Fluid Systems
http://webbook.nist.gov/chemistry/fluid/. Plot the NIST data along with the Peng-Robinson EoS
calculations on the same P-v plot. Compare the results and discuss the predictive accuracy of the PR
EOS.
The Peng-Robinson equation of state is given by
P=
RT
v-b
aa (T)
v(v+b)+b(v-b)
Here, a =
0.45724 R2T/P
b = 0.07780RT/P
a(T) = [1 + x(1 − √T/T)]
K = 0.37464 + 1.54226w - 0.26992w (wacentric factor)
Refer to chapter 4 of Koretsky 2nd edition for information about the PR equation of state.
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