تم الحل ✓
categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
3. A small reaction bomb (assumed to be constant volume) fitted with a sensitive pressure-measuring
device is filled with pure reactant A at 1.0 atm of pressure. The operation is carried out at 25°C, a
temperature low enough that the reaction does not proceed to any appreciable extent. The
temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water,
and the readings below were obtained. The stoichiometry of the reaction is 2A → B, and after
leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found.
t (min)
1
P (atm)
1.14
t (min)
P (atm)
6
0.870
2
1.04
7
0.850
3
0.982
8
0.832
4
0.940
9
0.815
5
0.905
10
0.800
a. Determine the rate equation in units of moles, liters, and minutes which will satisfactorily fit the
data.
b. Plot the concentrations of A and B versus time from t=0 to 10 min.
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