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categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
2.51 Consider a mixture of 25% ammonia, the rest nitrogen and hydrogen in a 1:3 ratio.
The gas is at 270 atm and 550 K. Use Excel (or MATLAB) to compute the specific
volume using
(a) ideal gas law
(b) Redlich-Kwong equation of state
(c) Redlich-Kwong-Soave equation of state.
Where did you get the data you needed? How do the three answers compare? Is the
gas ideal or not? Comment on the reasons the RKS equation might be expected to
be better.
TABLE 2.1 Equations of State for Pure Components
h
Model
EOS
Ideal gas
pV = nRT
RT
R-T
RT
van der Waal
p=
a=0.42188
b=0.125
8-h
N
Pe
RT
RT
Redlich-Kwong p
a-0.42748(
a b 0.08664
i-b
(+b)
P
RT
RK-Soave
P-
a=0.42748
a b 0.08664
8-6
0(+b)
0.375
0.333
a=[1+m(1-7)] m = 0.480
0.333
+1.574w
-0.176
RT
Peng-Robinson p=
a=0.45724
-b (+b)+b(-b)
()
a b 0.07780
80 (7) a = (1+m (1-795)]
m-0.37464
0.307
+1.542260)
-0.269922
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