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categoryهندسة كيميائية
schoolبكالوريوس
event_available2026-07-13
السؤال
Transcribed Image Text:
9A.9. Thermal conductivity of gaseous chlorine. Use
Eq. 9.3-15 to calculate the thermal conductivity of gaseous
chlorine. To do this you will need to use Eq. 1.4-14 to esti-
mate the viscosity, and will also need the following values
of the heat capacity:
T(K)
200 300 400 500 600
C, (cal/g-mole K) (8.06) 8.12 8.44 8.62 6.74
Check to see how well the calculated values agree with the
following experimental thermal conductivity data³
p (mm Hg) kx 10' cal/cm's K
T(K)
198
50
1.31 ± 0.03
275
220
1.90 ± 0.02
276
120
1.93 ± 0.01
220
1.92 ± 0.01
363
100
2.62 ± 0.02
200
2.61 ± 0.02
395
210
3.04 ± 0.02
453
150
3.53 ± 0.03
250
3.42 ± 0.02
495
250
3.72 ± 0.07
553
100
4.14 ± 0.04
583
170
4.43 ± 0.04
210
4.45 ± 0.08
676
150
5.07 ± 0.10
250
4.90 ± 0.03
miempirical metnoa or accounting for the energy excnange in poly-
s developed by Eucken. His equation for thermal conductivity of a
low density is
5 R
k = +
4M
(polyatomic gas)
(9.3-15)
cosity of a pure monatomic gas of molecular weight M may be written in
Lennard-Jones parameters as
P =>
5 √TINKT
16 πα
or -2.6693 x 10-5 VMT
στη
(1.4-14)
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