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categoryهندسة كيميائية schoolبكالوريوس event_available2026-07-15

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26.14 A spherical ball of solid, nonporous naphthalene, a "mothball," is suspended in still air. The naphthalene ball slowly sublimes, releasing the naphthalene vapor into the surrounding air by molecular diffusion-limited process. Estimate the time required to reduce the diameter from 2.0 to 0.50 cm when the surrounding air is at 347 K and 1.0 atm. Naphthalene has a molecular weight of 128 g/mol, a solid density of 1.145 g/cm³, and a diffusivity in air of 8.19 x 10-6 m²/s, and exerts a vapor pressure of 5.0 Torr (666 Pa) at 347 K.

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