تم الحل ✓
categoryالكيمياء
schoolبكالوريوس
event_available2026-07-15
السؤال
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Question #1 (Chemical Reaction equilibrium)(Multiple reaction) (100 marks)
The feed gas to a methanol synthesis reactor is composed of 75 mol % H2, 15 mol % CO,
5 mol% CO; and 5 mol% N₂(Inert). The system comes to equilibrium at 550 K and 100
bar with respect to the reactions (gas phase). Take basis of 1 mole or reactant mixture.
(1) 2Hz + CO→ CH; OH
(2) H2 + COI > CO + HỌ
extent of reaction &
extent of reaction
(a) Express the mole fraction of all the species in terms of and {? (20 marks)
(b) Find out the equilibrium constants K₁ and K₂ for the reactions? (50 marks)
(c) Assuming ideal gas determine the composition of the equilibrium mixture? (30
Marks)
T₁ = 298.15 K
Data: Heat capacities of gases in the ideal gas state
A+BT+ CT2+ DT-2)
Species
A
B
C
D
Hz
3.249
0.422x10
0
0.083x10
CO
3.376
0.557x10
0
-0.031 x10
CH₂OH
2.211
12.216x10
-3.45 x10
CO
5.457
1.045 x103
0
0
-1.157 x105
H₂O
3.47
1.45x10
°
0.121x10
N₂
3.28
0.593x10
0
0.04 x105
Standard enthalpy and Gibbs energy of formation (J/mol)
Species
AH 129
AG°12
H₂
0
0
CO
-110525
-137169
CH₂OH
-200660
-161960
CO₂
-393509
-394359
H₂O
-241818
-228572
N₂.
°
0
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