تم الحل ✓
categoryالكيمياء
schoolبكالوريوس
event_available2026-07-15
السؤال
Transcribed Image Text:
2. Consider the biosynthetic reaction between glutamate and NH4+ to form glutamine at T = 25° C (R =
8.3145 J/mol K),
glutamate +NH4* → glutamine
(a) The equilibrium constant for the reaction under standard biochemical conditions is Keq = 0.00325.
Calculate AG and please give your answer in kJ/mol.
AG°' =
kJ/mol
(b) To make the reaction spontaneous, what would the concentration of glutamine have to be
maintained at relative to the concentrations of glutamate and NH4*?
Relative concentration of glutamine =
(c) Show that the biosynthesis of glutamine can be made spontaneous by the addition of ATP, assuming
ATP spontaneously hydrolyzes to ADP and P; with (AG°' = -30.5 kJ/mol) at T = 25° C. In your final
answer, please give your answer in kJ/mol and include all reactants and products.
Write overall reaction:
Overall AG°' =
kJ/mol
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