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categoryكيمياء
schoolبكالوريوس
event_available2026-07-15
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Question 8
An acetoacetic ester synthesis of a ketone proceeds by alkylation of the enolate of the
acetoacetic ester followed by ester hydrolysis and decarboxylation of the B-ketoacid. Which
of the following methyl ketones is difficult to prepare by this method?
CH3CCH2C(CH3)3
CHỊCH,PH
CH3CH2CH2Ph
a)
O
b)
о
c)
O
d)
CH₂CCH2CH2CH=CH2
-CH=CH2
о
CH3CCH(CH₂Ph)2
Question 9
A malonic ester synthesis of a carboxylic acid proceeds by alkylation of the enolate of the
malonic ester followed by ester hydrolysis and decarboxylation of the B-dicarboxylic acid.
Which of the following carboxylic acids is difficult to prepare by this method?
O a) PhCH2CH2CO₂H
O b) (CH3)2CHCO₂H
O c) PhCH2CO₂H
CO₂H
d)
Question 10
a
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