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categoryالكيمياء schoolبكالوريوس event_available2026-07-15

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14) The equilibrium constant of the reaction 2 CrO4+2H+ Cr2072 + H2O is 4.1X1014. The molar absorptivities of the main species of a K2Cr2O7 solution are: λ(nm) 345 370 400 E1(CrO4) 1.84X10³ 4.81X10³ 1.88X10³ 82 (Cr207) 10.7X10² 7.28X10² 1.89X102 Four solutions were prepared by dissolving 4.00X10-4; 3.00X104; 2.00X10+ and 1.00X10-4 moles of K2Cr2O7 in water diluting up to 1.00 L with a buffer solution of pH 5.60. Deduce the theoretical absorbance values (cells of 1.00 cm) for each solution and plot the data for a) 345 nm, b) 370 nm and c) 400 nm.

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